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Kinetics of alkaline-catalyzed cardanol–formaldehyde reaction. III. Determination of composition of the resin

✍ Scribed by A. K. Misra; G. N. Pandey


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
174 KB
Volume
30
Category
Article
ISSN
0021-8995

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✦ Synopsis


In the present study, a quick method for the determination of composition of the resin formed by alkaline-catalyzed cardanol-formaldehyde reaction has been suggested. The complete analysis of the product could be carried out by determining experimentally the concentration of only one reactant, viz., formaldehyde present in the reaction mixture at any time.


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with respect to the catalyst concentration is first. The reaction mechanism supposes the formation of a complex between the substrate and the catalyst active form . Subsequently, the complex thus formed slowly decomposes in the rate determining step to give carbonium ions and ruthenium hydride, sinc