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Kinetics of Adsorption and Desorption of Poly(ethylenimine) and Its Complex with Copper(II) on Copper(II) Oxide Powder

✍ Scribed by V.N. Kislenko; R.M. Verlinskaya


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
56 KB
Volume
231
Category
Article
ISSN
0021-9797

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✦ Synopsis


Adsorption of poly(ethylenimine) and complexes of poly(ethylenimine) with copper(II) ions on copper(II) oxide powder has been investigated. The rate of adsorption and reaction between poly(ethylenimine) and

CuO is very fast. The desorption rate of the complex of poly(ethylenimine) with copper(II) ions is slower and decreases when the initial polymer concentration is decreased. The desorption rate passes through a minimum when the initial concentration of CuO powder in the mixture increases. A mathematical model of polymer adsorption and desorption is proposed.


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