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Kinetics of addition of butyllithium onto diisopropenylbenzene

✍ Scribed by P. Lutz; G. Beinert; E. Franta; P. Rempp

Book ID
103072622
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
388 KB
Volume
15
Category
Article
ISSN
0014-3057

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✦ Synopsis

The kinetics of the addition reaction between butyllithium and diisopropenylbenzene (DIB) were investigated in non-polar solvents. It has been established that the two double bonds of meta-DIB are almost isoreactive, as expected; for the para-isomer however the first addition is faster than the second. The overall rate of reaction is also greater for para-DIB, This kinetic study is of great use, since the diadduct behaves as an efficient bifunctional anionic initiator which can be used in non-polar solvents.

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