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Kinetics of 2-methylbutene-2 epoxidation with 2-methylbutane hydroperoxide

✍ Scribed by L. A. Petukhova; V. N. Sapunov; Kh. E. Kharlampidi; A. A. Petukhov

Book ID
110196904
Publisher
Springer
Year
2010
Tongue
English
Weight
249 KB
Volume
50
Category
Article
ISSN
0965-5441

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✍ LΓ­dia C. Albuquerque; Luisa C. Moita; Ana N. SimΓ΅es; Raquel C. GonΓ§alves; EugΓ©ni πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 91 KB πŸ‘ 1 views

Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info