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Kinetics of the reaction between dimethyldioxirane and 2-methylbutane

✍ Scribed by D. V. Kazakov; D. R. Khusnullina; N. N. Kabal'nova; S. L. Khursan; V. V. Shereshovets

Publisher
Springer
Year
1997
Tongue
English
Weight
294 KB
Volume
46
Category
Article
ISSN
1573-9171

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Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info