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Kinetics of 1,3-dipolar cycloaddition reactions of diazomethane; A correlation with homo-lumo energies

✍ Scribed by Jochen Geittner; Rolf Huisgen; Reiner Sustmann

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
211 KB
Volume
18
Category
Article
ISSN
0040-4039

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1,3-Dipolar cycloaddition of diazomethan
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## The chiral Z-azlactone derived from 1.2-0-isopropylidene-D-glyceraldehyde reacted with diazomethane to amrd stereoseiectively and diastereoselectively a cis Spiro-azlactone. Solvent and temperature &per&nce of the ratio of the producti is described e$-Didehydtoamino acid derivatives ate useful