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1,3-Dipolar cycloaddition of diazomethane with a chiral azlactone

✍ Scribed by Carlos Cativiela; María D Díaz-de-Villegas; Ana I Jiménez; Fernando Lahoz

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
314 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis

The chiral Z-azlactone derived from 1.2-0-isopropylidene-D-glyceraldehyde reacted with diazomethane to amrd stereoseiectively and diastereoselectively a cis Spiro-azlactone.

Solvent and temperature &per&nce of the ratio of the producti is described e$-Didehydtoamino acid derivatives ate useful pmchiral building blocks in synthetic organic chemisuy. In

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