𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2-Pyrazolines from 1,3 - dipolar cycloaddition of diazomethane to arylsulfonylethenes

✍ Scribed by Venkatapuram Padmavathi; Mudigonda Rajagopala Sarma; Adivireddy Padmaja; Dandu Bhaskar Reddy


Publisher
Journal of Heterocyclic Chemistry
Year
2003
Tongue
English
Weight
50 KB
Volume
40
Category
Article
ISSN
0022-152X

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Novel 2‐pyrazolines were obtained by the cycloaddition of diazomethane to bis(arylsulfonylethenyl)‐sulfones (3) and 1‐arylsulfonyl‐2‐styrylsulfonylethenes (7). Dehydrogenation of 2‐pyrazolines with chloranil gave pyrazoles.


📜 SIMILAR VOLUMES


Synthesis of spiro-1-pyrazolines by the
✍ Artur M. S. Silva; José A. S. Cavaleiro; Albert Lévai; Tamás Patonay 📂 Article 📅 1999 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 641 KB

## Abstract 1,3‐Dipolar cycloadditions of exocyclic α,β‐unsaturated ketones 1‐22 with diazomethane afforded spiro‐1‐pyrazolines 23‐44 in a diastereospecific reaction. The structure and stereochemistry of each compound synthesised has been elucidated by nmr spectroscopic measurements and other analy

Perturbational analysis of 1,3-dipolar c
✍ Reiner Sustmann; Egon Wenning; Rolf Huisgen 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 183 KB

Perturbational molecular orbital methods have furnished a clue to the problems of reactivity and regioselectivity in 1,34polar cycloadditions. 1 Within the framework of frontier molecular orbital theory 2 semiquantitative correlations of mte data with orbital energy sepamtions were obtained. In orde