## Abstract For Abstract see ChemInform Abstract in Full Text.
2-Pyrazolines from 1,3 - dipolar cycloaddition of diazomethane to arylsulfonylethenes
✍ Scribed by Venkatapuram Padmavathi; Mudigonda Rajagopala Sarma; Adivireddy Padmaja; Dandu Bhaskar Reddy
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2003
- Tongue
- English
- Weight
- 50 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
Novel 2‐pyrazolines were obtained by the cycloaddition of diazomethane to bis(arylsulfonylethenyl)‐sulfones (3) and 1‐arylsulfonyl‐2‐styrylsulfonylethenes (7). Dehydrogenation of 2‐pyrazolines with chloranil gave pyrazoles.
📜 SIMILAR VOLUMES
## Abstract 1,3‐Dipolar cycloadditions of exocyclic α,β‐unsaturated ketones 1‐22 with diazomethane afforded spiro‐1‐pyrazolines 23‐44 in a diastereospecific reaction. The structure and stereochemistry of each compound synthesised has been elucidated by nmr spectroscopic measurements and other analy
Perturbational molecular orbital methods have furnished a clue to the problems of reactivity and regioselectivity in 1,34polar cycloadditions. 1 Within the framework of frontier molecular orbital theory 2 semiquantitative correlations of mte data with orbital energy sepamtions were obtained. In orde