Radical polymerizations of a silicone-co
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Hiroshi Shiho; Joseph M. Desimone
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Article
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2000
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John Wiley and Sons
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English
β 144 KB
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Radical homopolymerizations and copolymerizations of 3-[tris(trimethylsilyloxy)silyl]propyl methacrylate (SiMA) in supercritical CO 2 were investigated. The homopolymer was obtained in CO 2 with a good yield. It was essentially insoluble in pure CO 2 at less than 500 bar at 65 Β°C but was soluble in