Kinetics and Thermodynamics of the Reaction between Iodine and Methane and the Heat of Formation of Methyl Iodide
โ Scribed by Goy, C. A.; Pritchard, H. O.
- Book ID
- 121440973
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 268 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
## Abstract The rate of the reaction of cyclopentadiene with iodine has been followed spectrophotometrically over the temperature range 171.7ยฐ to 276.5ยฐC. The reaction first proceeds almost to the point of equilibrium with cyclopentadienyl iodide and HI, although the final products are fulvalene an
The rate of the gas phase reaction A-CH,-I + I . 5 A-CH~. + I, has been measured spectrophotometrically over the range 480ยฐ-5500K. fits the equation log k (M-l sec-l) = 11.4 f 0.1 -(16.8 i 0.2)/8 where e = 2.303RT in kcal/mole. This result, together with the assumption that the activation energy fo
The gas-phase reaction CH3SH + IZ has been studied spectrophotometrically over the temperature range of 476-604 K. It was found that the reaction undergoes H abstraction by I at 5575 K, leading to the formation of MeSI and followed by a secondary reaction which leads to the formation of MeSSMe: Tak