Kinetics and thermodynamics of the reaction between iodine and fluoroform and the heat of formation of trifluoromethyl iodide
โ Scribed by Goy, C. A.; Lord, Allan; Pritchard, Huw O.
- Book ID
- 120296378
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 382 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The rate of the reaction of cyclopentadiene with iodine has been followed spectrophotometrically over the temperature range 171.7ยฐ to 276.5ยฐC. The reaction first proceeds almost to the point of equilibrium with cyclopentadienyl iodide and HI, although the final products are fulvalene an
The rate of the gas phase reaction A-CH,-I + I . 5 A-CH~. + I, has been measured spectrophotometrically over the range 480ยฐ-5500K. fits the equation log k (M-l sec-l) = 11.4 f 0.1 -(16.8 i 0.2)/8 where e = 2.303RT in kcal/mole. This result, together with the assumption that the activation energy fo
## Abstract For Abstract see ChemInform Abstract in Full Text.