Kinetics and thermochemistry of the addition of atomic chlorine to acetylene
โ Scribed by Yide Gao; I.M. Alecu; P.-C. Hsieh; A. McLeod; Chris McLeod; Maxwell Jones; Paul Marshall
- Book ID
- 108255091
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 396 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1540-7489
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The shock tube data of Ogura [51 on the pyrolysis of CzHz/NO mixtures (1100-1500 K) is shown to be consistent with a simple mechanism whereby radicals are both initiated and terminated by NO (Scheme I). The scheme accounts for the rate of formation of the main product, vinylacetylene (VA), the lesse
The process of two-and three-particle photorecombmation of chlorine atoms in a reftected shock wave and in a supersonic nozzle has been studied. The rate constants of photorecombinahon betaeen 960 K and 2800 K have been determmed experimentally for the first time. The contriiu~on of A and B states o
The mun reaction products resulting from the addition of ~tomrc hydrogen to acetylene are shown to be ethylene, l&butadiene, and benzene\_ The mechankm mvolves chain reactions of the vinyl and butadienyl radrals, which regenemte atomic hydrogen\_ Some of the rate psrameters are estimated