3-Methylfuran has been identified as a product of the gas-phase reaction of the OH radical with isoprene, and under simulated atmospheric conditions a formation yield of 0.044 -t 0.006 was determined. In an analogous manner, the OH radical reaction with 1,3-butadiene formed furan with a yield of 0.0
Kinetics and Products of the OH Radical-Initiated Reaction of 1,4-Butanediol and Rate Constants for the Reactions of OH Radicals with 4-Hydroxybutanal and 3-Hydroxypropanal
β Scribed by Mason, Sherri A.; Arey, Janet; Atkinson, Roger
- Book ID
- 126094633
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 350 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0013-936X
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π SIMILAR VOLUMES
The kinetics of the reactions of hydroxy radicals with cyclopropane and cyclobutane has been investigated in the temperature range of 298-492 K with laser flash photolysidresonance fluorescence technique. The temperature dependence of the rate constants is given by k l = (1.17 ? 0.15) x T3'' exp[-(1
Rate constants for the reactions of 0, and OH radicals with acetylene, propyne, and 1-butyne have been determined at room temperature. The rate constants obtained a t 294 i 2 K for the reactions of 0, with acetylene, propyne, and 1-butyne were (7.8 -c 1.2) x lo-'' cm3/molecule . s, (1.43 2 0.15) x l