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Kinetics and products of the complexation of pentaaqua(cyanomethyl)chromium(2+) by pyrophosphate and phosphate ions

✍ Scribed by Sisley, M. J.; Jordan, Robert B.

Book ID
127079795
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
631 KB
Volume
27
Category
Article
ISSN
0020-1669

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✍ Peter J. Hansen; James P. Birk πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 536 KB

The kinetics of the aquation of (HzO)&r(OzCCCl#+ have been examined at 35-55OC and 1.OOM ionic strength with [H+] = 0.01-1.OOM. The reaction follows the rate equation -d , where [Cr, , ] is the stoichiometric concentration of the complex. At 45OC a = (1.41 f 0.03) X 10-7M/s, b = (1.66 f 0.02) X 5-1