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Kinetics and products of the anation of pentaaqua(cyanomethyl)chromium(2+) by hypophosphite

โœ Scribed by Sisley, M. J.; Jordan, R. B.

Book ID
127396032
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
560 KB
Volume
26
Category
Article
ISSN
0020-1669

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๐Ÿ“œ SIMILAR VOLUMES

Kinetics and mechanism of the aquation o
Kinetics and mechanism of the aquation of pentaaqua (trichloroacetato-O)-chromium(2+) ion
โœ Peter J. Hansen; James P. Birk ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 536 KB

The kinetics of the aquation of (HzO)&r(OzCCCl#+ have been examined at 35-55OC and 1.OOM ionic strength with [H+] = 0.01-1.OOM. The reaction follows the rate equation -d , where [Cr, , ] is the stoichiometric concentration of the complex. At 45OC a = (1.41 f 0.03) X 10-7M/s, b = (1.66 f 0.02) X 5-1