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Kinetics and Mechanisms of the Pyridinolysis of Phenyl and 4-Nitrophenyl Chlorothionoformates. Formation and Hydrolysis of 1-(Aryloxythiocarbonyl)pyridinium Cations

✍ Scribed by Castro, Enrique A.; Cubillos, María; Santos, José G.


Book ID
126277623
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
97 KB
Volume
69
Category
Article
ISSN
0022-3263

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Kinetics and mechanism of the aminolysis
✍ Enrique A. Castro; Leonardo Leandro; José G. Santos 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k