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Kinetics and Mechanisms of S(IV) Reductions of Bromite and Chlorite Ions

✍ Scribed by Huff Hartz, Kara E.; Nicoson, Jeffrey S.; Wang, Lu; Margerum, Dale W.

Book ID
121319372
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
163 KB
Volume
42
Category
Article
ISSN
0020-1669

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✍ IstvΓ‘n NagypΓ‘l; Irving R. Epstein; Kenneth Kustin πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 396 KB

The kinetics of the oxidation of S20:-by CIOz-have been studied in aqueous alkaline solution at 90Β°C using classical titrimetric methods to follow the course of the reaction. The reaction takes place according to the stoichiometry SzO: - + 2C10z-+ 20H-= 2S042-+ 2Cl-+ H 2 0 even in large SzO:excess.