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Kinetics and mechanisms of reduction of metmyoglobins. Importance of the geometry change at the heme iron site upon reduction

โœ Scribed by Tsukahara, Keiichi


Book ID
126064070
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
629 KB
Volume
111
Category
Article
ISSN
0002-7863

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Two diametrically different pH dependences have been reported for oxygen reduction at prereduced Pt electrodes. In the current density (cd) region with the Tafel slope of -2.3RT/F, the pH dependence expressed as dE/dpH is, according to one group of workers, -90 mV, ie -3 x 2.3 RT/(2F) and -30 mV, ie