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Kinetics and mechanisms of oxidation by metal ions. Part XIV(1). Osmium(VIII)-catalysed oxidation of cycloalkanones by alkaline hexacyanoferrate(III)

โœ Scribed by Satya Pal S. Mehta,Raj N. Mehrotra

Book ID
126336765
Publisher
Springer
Year
1992
Tongue
English
Weight
977 KB
Volume
17
Category
Article
ISSN
0340-4285

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Kinetics and mechanisms of oxidation by metal ions, part XII [1] oxidation of formaldehyde by alkaline osmium(VIII)
โœ Minakshi Vishnoi; Kamla Sharma; Raj N. Mehrotra ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 622 KB

The stopped-flow measurements on the disappearance of alkaline osmium(VII1) at 402 nm indicated a first-order dependence each in [Os(VIII)] and [HCHO]. The pseudo first-order rate constant hobs ([HCHO] & [Os(VIII)]) decreased with increasing [OH-]. The ionic strength, however, had no effect on kobs.