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Kinetics and mechanisms of Cu(I)/O2 reactions

✍ Scribed by A.D. Zuberbühler

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
66 KB
Volume
47
Category
Article
ISSN
0162-0134

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✍ Yu. M. Gershenzon; S. D. Il'in; O. P. Kishkovitch; R. T. Malkhasyan JR.; V. B. R 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 856 KB

A combined EPR-LMR spectrometer with a fast-flow system has been used to investigate the kinetics and mechanisms of NF2 reactions with 0 and N atoms a t 298 K. The overall rate constants of these reactions are: ko = (2.8 f 0.4) X lo-" cm3/s and k~ = (5.7 f 0.8) X lo-" cm3/s. The stoichiometry of the