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The kinetics and mechanisms of elementary NF2 reactions with O and N atoms

✍ Scribed by Yu. M. Gershenzon; S. D. Il'in; O. P. Kishkovitch; R. T. Malkhasyan JR.; V. B. Rozenshtein; S. Ya. Umanskii

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
856 KB
Volume
15
Category
Article
ISSN
0538-8066

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✦ Synopsis

A combined EPR-LMR spectrometer with a fast-flow system has been used to investigate the kinetics and mechanisms of NF2 reactions with 0 and N atoms a t 298 K. The overall rate constants of these reactions are: ko = (2.8 f 0.4) X lo-" cm3/s and k~ = (5.7 f 0.8) X lo-" cm3/s. The stoichiometry of the reactions with respect to 0, N, NF2, F, and NO has been determined. The statistical theory of bimolecular reactions has been used for interpretation of the results obtained.

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