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Kinetics and Mechanisms of Chlorine Dioxide Oxidation of Tryptophan

✍ Scribed by Stewart, David J.; Napolitano, Michael J.; Bakhmutova-Albert, Ekaterina V.; Margerum, Dale W.

Book ID
121274122
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
231 KB
Volume
47
Category
Article
ISSN
0020-1669

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The stoichiometry and kinetics of the oxidation of thiourea (SC(NH2)z) by chlorine dioxide (ClOz) have been studied by uv-vis spectrophotometry using conventional and stopped-flow mixing techniques at 25.0 ? O.l"C, pH 0.3-4.8. In high acid and initial 10 : 1 molar ratio of thiourea to chlorine dioxi