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Kinetics and Mechanisms for the Cleavage and Isomerization of the Phosphodiester Bonds of RNA by Brønsted Acids and Bases

✍ Scribed by Oivanen, Mikko; Kuusela, Satu; Lönnberg, Harri

Book ID
126310612
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
908 KB
Volume
98
Category
Article
ISSN
0009-2665

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The isomerization of α-pinene oxide with
The isomerization of α-pinene oxide with Brønsted and Lewis acids
✍ J. Kaminska; M. A. Schwegler; A. J. Hoefnagel; H. van Bekkum 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 542 KB

## Abstract α‐Pinene oxide (2) is a very reactive substrate which isomerizes rapidly under the influence of acid catalysts. A large number of products can be formed from a single intermediate. Selectivity to the industrially important campholenic aldehyde can be achieved with metal‐halogen compound