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Kinetics and mechanism ofL-isoleucine oxidation by alkaline diperiodatoargentate(III)

โœ Scribed by Suresh D. Kulkarni; Sharanappa T. Nandibewoor

Book ID
106547360
Publisher
Springer
Year
2007
Tongue
English
Weight
289 KB
Volume
33
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of oxidation of n
Kinetics and mechanism of oxidation of nitrilotriacetic acid by diperiodatoargentate(III)
โœ Anil Kumar; Paresh Kumar ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 80 KB ๐Ÿ‘ 2 views

Diperiodatoargentate(III) oxidizes nitrilotriacetic acid in a mildly basic medium to produce formaldehyde and ammonia. This reaction follows a complex kinetic behaviour. The axial binding of NTA to silver(III) complex takes place on the millisecond time-scale with a second-order rate constant of (4.