Kinetics and Mechanism of Zn(II) Ions Electroreduction Catalyzed by Organic Compounds
β Scribed by G. Dalmata
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 173 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1040-0397
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The oxidation of ethylenediamine by diperiodatoargentate (III) ion has been studied by stopped-flow spectrophotometry. Kinetics of this reaction involves two steps. The first step is the complexation of silver (III) with the substrate and is over in about 10 ms. This is followed by a redox reaction
## Abstract The kinetics and mechanism of oxidation of iminodiacetic acid and __N__βmethyliminodiacetic acid by aquasilver(II) and Ag(II)β2,2β²βbipyridine complexes has been investigated. The results are discussed with reference to the active reaction pathways, the equilibrium quotient of the title