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Kinetics and mechanisms of oxidation of organic compounds by silver(II) species. Part VI: Iminodiacetic acid and N-methyliminodiacetic acid

✍ Scribed by Claudio Baiocchi; Giuseppe Bovio; Edoardo Mentasti

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 746 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550140907

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✦ Synopsis

Abstract

The kinetics and mechanism of oxidation of iminodiacetic acid and N‐methyliminodiacetic acid by aquasilver(II) and Ag(II)‐2,2′‐bipyridine complexes has been investigated. The results are discussed with reference to the active reaction pathways, the equilibrium quotient of the title reactions, the protolytic equilibria which involve the oxidizing complex, and the intrinsic self‐exchange rates of the oxidants.

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Kinetics of oxidation of organic compoun

Kinetics of oxidation of organic compounds by silver(II) in aqueous perchloric acid solution. IV. Aliphatic alcohols

✍ Claudio Baiocchi; Edoardo Mentasti 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 611 KB

## Abstract The kinetics and mechanism of the silver(II) oxidation of methanol, ethanol, 1‐propanol, 1‐methyl‐ ethanol, 1‐butanol, 2‐methyl‐1‐propanol, 2‐butanol, 2‐methyl‐2‐propanol, D~4~‐methanol, and D~6~‐methanol have been investigated at 8.0 and 20.0°C in aqueous perchloric acid media (1.00 ≤