The thermal gas-phase reaction of CF,OF with CCI,CC12 h a s been studied between 313.8 a n d 343 8 K The initial pressure of CF,OF was varied between 10.8 a n d 77.5 torr a n d that of CCI;,CCI, between 3.7 a n d 26 8 torr. CF,OF was always present in excess, varying t h e initial ratio of CF,OF t o
Kinetics and mechanism of the thermal gas-phase oxidation of 1,1-dichlorodifluoroethene, CF2CCl2, by molecular oxygen in the presence of trifluoromethylhypofluorite, CF3OF
β Scribed by Czarnowski, Joanna
- Book ID
- 126052633
- Publisher
- The Royal Society of Chemistry
- Year
- 1989
- Weight
- 860 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0300-9238
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π SIMILAR VOLUMES
The kinetics of the gas phase reaction between NOz and CFzCCIz has been investigated in the temperature range from 50 to 80Β°C. The reaction is homogeneous. Three prod- and equimolecular amounts of ClNO and of OZNCFZC(O)CI. The rate of consumption of the reactants is independent of the total pressur
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products