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Kinetics and mechanism of the sulfite-induced autoxidation of cobalt(II) in aqueous azide medium

✍ Scribed by Coichev, Nina.; Van Eldik, Rudi.


Book ID
121235925
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
683 KB
Volume
30
Category
Article
ISSN
0020-1669

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Mechanism of the azide–bromine reaction
✍ T. S. Vivekanandam; U. Chandra Singh; M. S. Ramachandran πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 310 KB

## Abstract Results on the oxidation of N by Br~2~ in neutral and acid media are presented. The rate of the reaction is found to be proportional to [N] and [Br~2~]. The gaseous product of oxidation is found to be pure nitrogen. The stoichiometry of the reaction is The reaction shows a positive sa