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Kinetics and mechanism of the reduction of dodecatungstocobaltate(III) by α-hydroxyacids in aqueous acid solution. Evidence for alkali metal ion catalysis

✍ Scribed by Mala Gupta; Swapan K Saha; Pradyot Banerjee


Publisher
Springer
Year
1991
Tongue
English
Weight
442 KB
Volume
16
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of the reduction
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The reaction between tetrachloroaurate(III) and malonic acidfmalonate ion was studied kinetically over a wide range of temperatures, malonate, hydrogen and chloride ion concentrations at ionic strength 1.0 M. The suggested reaction mechanism consists of a series of substitution reactions during whic