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Kinetics and Mechanism of the Reaction of the Hydroxyl Radical with h 8 -Isoprene and d 8 -Isoprene: Isoprene Absorption Cross Sections, Rate Coefficients, and the Mechanism of Hydroperoxyl Radical Production

โœ Scribed by Campuzano-Jost, P.; Williams, M. B.; D'Otton, L.; Hynes, A. J.


Book ID
126058045
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
721 KB
Volume
108
Category
Article
ISSN
1089-5639

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Using a relative rate method, rate constants for the gas-phase reactions OF the NO, radical with methacrolein and methyl vinyl ketone were determined to be ( 4 4 2 1.7) X cm' molecule-' s-' and < 6 X cm3 molecule-' S S ' , respectively, at 296 ? 2 K. The molar formation yields of rnethacrolein and m