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Kinetics and mechanism of the reaction of diphenylcarbene with [1.1.1]propellane

✍ Scribed by McGarry, P. F.; Johnston, L. J.; Scaiano, J. C.

Book ID
125935314
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
256 KB
Volume
111
Category
Article
ISSN
0002-7863

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Reaction of phenylchlorocarbene with [1.
Reaction of phenylchlorocarbene with [1.1.1] propellane: Absolute rate constants and mechanism
✍ J.C Scaiano; P.F. McGarry πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 241 KB

Phenylchlorocarben e adds to [l.l.l] propellane with rate constants of 6.1 x 107 and 8.8 x 106 M-ts-1 in cyclohexane and acetonibile respectively to pmduce adduct V in good yields No evidence for a biradicalintem&iatewasob@ined.