Kinetics and mechanism of the phase-transfer-catalyzed carbonylation of benzyl bromide by cobalt tetracarbonyl anion
β Scribed by Des Abbayes, Herve; Buloup, Anne; Tanguy, Guy
- Book ID
- 127354109
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 886 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
The phase transfer catalyzed, cobalt carbonyl catalyzed carbonylation (1 atm. P.) of aryl and vinyl bromides under photostimulation (350 nm) affords the corresponding unsaturated acids in high yield. Recent investigations have demonstrated that phase transfer catalysis is a useful technique in organ
Sunsnary: Phase transfer catalyzed reaction of vinyl epoxides with carbon monoxide, methyl iodide, catalytic amounts of cobalt carbonyl and TDA-1, affords B-hydroxy acids. High regioselectivity was observed in some cases. Phase transfer catalysis is a valuable method for effecting metal catalyzed