Kinetics and mechanism of cobalt bromide catalyzed oxidation of p-xylene in the presence of phase transfer catalysts
✍ Scribed by M. Haruštiak; M. Hronec; J. Ilavaky
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 632 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0304-5102
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The homogeneous metal/bromide-catalyzed aerobic oxidation of p-xylene with different catalyst concentrations was carried out, and the formation kinetics of CO x including CO 2 and CO was measured. The simplified elementary steps for the formation of CO x were summarized, on the basis of which the ki
The oxidation of perfluorobutene-2 (C 4 F 8 ) initiated by trifluoromethyl hypofluorite (CF 3 OF) in presence of O 2 has been studied at 323.1, 332.6, 342.5, and 352.0 K, using a conventional static system. The initial pressure of CF 3 OF was varied between 4.8 and 23.6 Torr, that of C 4 F 8 between
## Abstract A detailed radical chain elementary reaction mechanism for the liquid‐phase catalytic oxidation of meta‐xylene to meta‐phthalic acid catalyzed by cobalt acetate and manganese acetate and promoted by hydrogen bromide was proposed. Using several reasonable assumptions a simple fractional‐