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Kinetics and Mechanism of the Oxygenation of Potassium Flavonolate. Evidence for an Electron Transfer Mechanism

✍ Scribed by Barhács, László; Kaizer, József; Speier, Gábor

Book ID
126892152
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
100 KB
Volume
65
Category
Article
ISSN
0022-3263

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Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.