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Kinetics and mechanism of the oxidation of some diols by benzyltrimethylammoniumtribromide

✍ Scribed by Garima Goswami; Seema Kothari; Kalyan K Banerji

Book ID
110644515
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2001
Tongue
English
Weight
91 KB
Volume
113
Category
Article
ISSN
0253-4134

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The kinetics of oxidation of four vicinal diols, four nonvicinal diols, and one of their monoethers by pyridinium bromochromate (PBC) have been studied in dimethyl sulfoxide. The main product of oxidation is the corresponding hydroxyaldehyde. The reaction is first-order with respect to each the diol

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Kinetics and Mechanism of Oxidation of Some Diols by Dihydroxydiperiodatoargentate(III) in Alkaline Medium
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