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Kinetics and Mechanism of the Oxidation of Guanosine Derivatives by Pt(IV) Complexes

โœ Scribed by Choi, Sunhee; Vastag, Livia; Leung, Chin-Hin; Beard, Adam M.; Knowles, Darcy E.; Larrabee, James A.


Book ID
120888632
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
275 KB
Volume
45
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of the oxidation
โœ Sridevi Nadimpalli; Rambabu Rallabandi; L. S. A. Dikshitulu ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Springer ๐ŸŒ English โš– 444 KB

The oxidation of selenium(IV) by permanganate has been studied kinetically in acid, neutral and alkaline media. The reaction exhibits unit-order dependence on selenium(IV) and permanganate in all the three media. Manganese(VI) retards the reaction in alkaline medium. The rate-limiting step is the sa