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Kinetics and mechanism of oxidation of 8-hydroxyquinoline and its derivatives by cerium(IV) through precursor complex formation

โœ Scribed by Ashis K. Pondit; Asim Das; Debabrata Banerjea

Book ID
105042041
Publisher
Springer
Year
1991
Tongue
English
Weight
415 KB
Volume
16
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of cerium(IV) oxi
Kinetics and mechanism of cerium(IV) oxidation of primary and secondary alcohols catalysed by chromium(III)
โœ Laxman V. Nimbalkar; Anant M. Chavan; Gavisiddappa S. Gokavi ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 115 KB ๐Ÿ‘ 2 views

The cerium(IV) oxidation of isobutanol, isoamyl alcohol isopropyl alcohol, and secondary butanol catalysed by chromium(III) was studied in sulphuric and perchloric acid mixture at 30 ยฐC. The reaction was found to proceed with the formation of a chromium(IV) intermediate followed by its complexation