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Kinetics and mechanism of the oxidation of ethyl xanthate and ethyl thiocarbonate by hydrogen peroxide

✍ Scribed by Silvester, Ewen; Truccolo, David; Hao, Fu Ping

Book ID
118047435
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
543 KB
Volume
9
Category
Article
ISSN
1472-779X

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The kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0ЊC are studied. Relatively small values of ␀ X (␀ nuc ) Ο­ 0.6 Ο³ 0.8 and ␀ Z (␀ lg ) Ο­ Οͺ0.5 Ο³ Οͺ0.7 together with a negative cross-interaction constant XZ (Ο­ Οͺ0.47) and failure o