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Kinetics and Mechanism of the One-Electron Reduction of Iodine by [Ru II (NH 3 ) 5 isn] 2+ in Aqueous Solution

โœ Scribed by Sun, Jiafei; Stanbury, David M.


Book ID
126320245
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
119 KB
Volume
37
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of the reductions
โœ Adedayo B. Adegboro; J.Folorunso Ojo; Olusegun Olubuyide; Oluyemisi T. Sheyin ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 432 KB

The reductions of azido-and isothiocyanato-pentacyanocobaltate(II1) by hexaammine-and aquapentaammineruthenium(I1) have been investigated in aqueous solution at I = 0.20 mol dmm3 (LiCl) and the values at 25 "C of the rate constants (dm3 mol-' s-l) are ky = 1.71 and kNCs = 0.8 1 for the Ru(NH~)~~+ re