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Quantum-Chemical Study of the Electronic Structure of the Complex Ions [Ru(NH3)5pyz]2+and [Ru(CN)5pyz]3-in Solution

✍ Scribed by O. V. Sizova; V. I. Baranovskii; N. V. Ivanova; V. V. Sizov; A. Yu. Ershov; A. D. Shashko; A. B. Nikol'skii

Book ID: 110437217
Publisher: Springer
Year: 2002
Tongue: English
Weight: 114 KB
Volume: 72
Category: Article
ISSN: 1070-3632
DOI: 10.1023/a:1023430305295

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## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i