Kinetics and Mechanism of the OH + C 6 H 6 Reaction: A Detailed Analysis with First-Principles Calculations
β Scribed by Tokmakov, I. V.; Lin, M. C.
- Book ID
- 126081948
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 330 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The distributions of relative translational energy released during (i) loss of H, from metastable CH,CHi' ions, (ii) loss of HD from metastable CH,CDl' ions and (iii) loss of D, from metastable CD,CDl' ions ?.ere measured. The relevant parts of the potential energy surface of the reaction C,H:' + C
The rate constants for the reaction of with HBr and DBr have been measured with the cavityring-down method in the temperature range of 297 to 523 K and 297 to 500 K, respectively. These rate constants can be effectively represented, in units of cm3/s, by exp[(-554 2 208)/T] and kHLlr = 10-10.40?0.24