Kinetics and mechanism of the liquid-phase oxidation op bibenzyl
β Scribed by S. R. Serglenko; N. Ya. Chernyak
- Book ID
- 112436831
- Publisher
- Springer
- Year
- 1959
- Tongue
- English
- Weight
- 688 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Liquid-phase oxidation is discussed in terms of the free radical chain mechanism proposed by BOLLAND and his co-workers. This scheme was devised for certain oxidations in which hydroperoxide is the major product. It is shown, however, that this mechanism is applieable in its essentials to other oxid
## Abstract A study was made of the rate of liquidβphase oxidation of ethanol to acetic acid. An aqueous, basic solution of ethanol was allowed to trickle over a palladiumβonalumina catalyst in a packed tower while oxygenβcontaining gas was blown upward. The observed rates are described by an equat