𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and mechanism of the liquid-phase oxidation ofn-carboxylic acids

✍ Scribed by Yu. V. Nepomnyashchikh; S. V. Puchkov; O. V. Abdulova; A. L. Perkel’


Book ID
110171127
Publisher
Springer
Year
2009
Tongue
English
Weight
266 KB
Volume
50
Category
Article
ISSN
0023-1584

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The mechanism of liquid-phase oxidation
✍ G.H. Twigg 📂 Article 📅 1954 🏛 Elsevier Science 🌐 English ⚖ 1000 KB

Liquid-phase oxidation is discussed in terms of the free radical chain mechanism proposed by BOLLAND and his co-workers. This scheme was devised for certain oxidations in which hydroperoxide is the major product. It is shown, however, that this mechanism is applieable in its essentials to other oxid

Kinetics of the liquid-phase oxidation o
✍ John Klassen; R. S. Kirk 📂 Article 📅 1955 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 823 KB

## Abstract A study was made of the rate of liquid‐phase oxidation of ethanol to acetic acid. An aqueous, basic solution of ethanol was allowed to trickle over a palladium‐onalumina catalyst in a packed tower while oxygen‐containing gas was blown upward. The observed rates are described by an equat

Reaction mechanism and kinetics for the
✍ Qinbo Wang; Yongzhao Zhang; Youwei Cheng; Xi Li 📂 Article 📅 2008 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 582 KB

## Abstract A detailed radical chain elementary reaction mechanism for the liquid‐phase catalytic oxidation of meta‐xylene to meta‐phthalic acid catalyzed by cobalt acetate and manganese acetate and promoted by hydrogen bromide was proposed. Using several reasonable assumptions a simple fractional‐