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Kinetics and Mechanism of the Insertion Reaction of Arylisocyanates into C‒C Bond of Phosphabetaine Obtained ont the Basis of Triisopropylphosphine and 2-Cyanoethylacrylate

✍ Scribed by Galkin, V. I.; Bakhtiyarova, Yu. V.; Gogololobov, Yu. G.; Polezaheva, N. A.; Cherkasov, R. A.

Book ID
127176052
Publisher
Taylor and Francis Group
Year
1999
Tongue
English
Weight
82 KB
Volume
147
Category
Article
ISSN
1042-6507

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Kinetics and mechanism of the unusual in
Kinetics and mechanism of the unusual insertion reactions of aryl isocyanates into the CC bond of the phosphonium zwitter-ion derived by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate
✍ V. I. Galkin; Yu. V. Bakhtiyarova; Yu. G. Gololobov; N. A. Polezhaeva; R. A. Che 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB 👁 2 views

The kinetics of the reactions of aryl isocyanates with the zwitterion formed by the addition of triisopropylphosphine to ethyl 2-cyanoacrylate in acetonitrile solution have been determined by a spectrophotometric method. It was established that the reaction is second order overall, first order with