Kinetics and Mechanism of the Epoxidation of Allylic Alcohols by Hydrogen Peroxide with Methyltrioxorhenium as Catalyst
β Scribed by Riley Tetzlaff, Heather; Espenson, James H.
- Book ID
- 127024052
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 132 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
## Abstract The influence of the technological parameters on the course of the epoxidation of allyl alcohol with 30% H~2~O~2~ in the presence of titanium silicalite TSβ2 catalyst and methanol as a solvent was studied. The process was performed in an autoclave at the autogenic pressure. The influenc
Peroxotungstic acid and quaternary ammonium peroxotungstic salts when complexed to organophosphorus(V) ligands exhibit enhanced reactivity and selectivity in the epoxidation of unsaturated alcohols with hydrogen peroxide. The organophosphorus ligands contain the phosphoryl O=P= subunit as complexing