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Nb(salan)-Catalyzed Asymmetric Epoxidation of Allylic Alcohols with Hydrogen Peroxide

✍ Scribed by Hiromichi Egami; Tsutomu Katsuki

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 411 KB
Volume: 120
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200800797

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## Abstract The highly chemo‐, regio‐, and diastereoselective and stereospecific epoxidation of various allylic alcohols with only one equivalent of hydrogen peroxide in water can be efficiently catalyzed by the dinuclear peroxotungstate, K~2~[{W(O)(O~2~)~2~(H~2~O)}~2~(μ‐O)]⋅ 2 H~2~O (I). The cata