𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and Mechanism of the Anilinolysis of Aryl 4-Nitrophenyl Carbonates in Aqueous Ethanol

✍ Scribed by Castro, Enrique A.; Gazitúa, Marcela; Santos, José G.

Book ID
120552182
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
98 KB
Volume
70
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Anilinolysis of reactive aryl 2,4-dinitr
Anilinolysis of reactive aryl 2,4-dinitrophenyl carbonates: Kinetics and mechanism
✍ Enrique A. Castro; Claudia Domecq; José G. Santos 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 108 KB

The reactions of a series of anilines with phenyl 2,4-dinitrophenyl (1), 4-nitrophenyl 2,4-dinitrophenyl (2), and bis(2,4-dinitrophenyl) (3) carbonates are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0 ± 0.1 • C and an ionic strength of 0.2 M. Under amine excess pseudo-first-

Kinetics and mechanism of the aminolysis
Kinetics and mechanism of the aminolysis of 4-nitrophenyl and 2,4-dinitrophenyl 4-methylphenyl carbonates in aqueous ethanol
✍ Enrique A. Castro; Monica Andujar; Paola Campodonico; José G. Santos 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

## Abstract The reactions of 4‐methylphenyl 4‐nitrophenyl carbonate (MPNPC) and 4‐methylphenyl 2,4‐dinitrophenyl carbonate (MPDNPC) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol–water, at 25.0°C, ionic strength 0.2 M (KCl). Under amine excess

Kinetics and mechanism of the aminolysis
Kinetics and mechanism of the aminolysis of O-phenyl 4-nitrophenyl dithiocarbonate in aqueous ethanol
✍ Enrique A. Castro; Leonardo Leandro; José G. Santos 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k

Stepwise mechanisms of the aminolyses of
Stepwise mechanisms of the aminolyses of 4-Nitrophenyl and 2,4-Dinitrophenyl O-Ethyl Dithiocarbonates in aqueous Ethanol
✍ Enrique A. Castro; Gabriel MuñOz; Mirtha Salas; Jose G. Santos 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 432 KB

## Abstract The reactions of the title substrates with a series of secondary alicyclic amines are subjected to a kinetic study in 44 wt% aqueous ethanol, at 25.0deg;C, ionic strength 0.2 M (maintained with KCl). Pseudo‐first‐order kinetics are found under amine excess. The order in amine obtained i