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Kinetics and Mechanism of St I Modification by Peroxyl Radicals

✍ Scribed by A. M. Campos; E. A. Lissi; C. Vergara; M. E. Lanio; C. Alvarez; I. Pazos; V. Morera; Y. García; D. Martinez

Book ID
110403494
Publisher
Springer
Year
1999
Tongue
English
Weight
853 KB
Volume
18
Category
Article
ISSN
1573-4943

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✍ K. Schwetlick; J. Pionteck; T. König; W.D. Habicher 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 387 KB

Alrstract--Trialkyl phosphites react with cyanoisopropylperoxyl radicals, generated by thermolysis of azobis(isobutyronitrile) in the presence of oxygen, to give the corresponding phosphates with rate constants of the order of 103 M -~ sec -~ at 65°C. Phenyl phosphites are oxidized also. A small amo