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Kinetics and mechanism of replacement of W(VI) in the heteropolyanion PW12O403−

✍ Scribed by O. A. Kholdeeva; I. V. Kozhevnikov


Book ID
112444188
Publisher
Springer
Year
1986
Tongue
English
Weight
481 KB
Volume
35
Category
Article
ISSN
1573-9171

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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ЊC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H ϩ ]. The order with respect to [HClO 4 ]