Kinetics and mechanism of reaction of m-nitrobenzhydrazide and other hydrazines with acetic acid
β Scribed by Thomas Medwick; Hamed M. Abdou
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 749 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3549
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The equilibrium constant for the reaction CH,(COOH), + I J -@ CHI(CO0H)Z + 21-+ H+, measured spectrophotometrically at 25OC and ionic strength 1.00M (NaC104), is (2.79 f 0.48) X 10-'M2. Stopped-flow kinetic measurements a t 25OC and ionic strength 1.OOM with [H+] = (2.09-95.0) X lO-3M and [I-] = (1.
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